A section of four-rail 630v DC electrified track on London Underground's District Line at Earl's Court station.
From top to bottom the four rails are:
The diamond between the negative and left-hand running rail is the train stopping mark - where the front of the train should be to ensure the entire train is in the platform and aligned with the monitors, etc.

A good explanation of the reasons behind the four-rail electrification system can be found on the Tubeprune website.

Photo by Chris McKenna 20/08/2005. Larger, higher quality copies of most of my pictures are available, please email if you want a copy. #cmckenna@sucs.org